Homogeneous isotopic exchange between nickel(II) and bis(resacetophenone oxime) nickel(II) complex |
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| Authors: | T Gangaiah G R K Naidu K Venugopal Chetty |
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| Institution: | 1. Chemistry Department, College of Engineering, Sri Venkateswara University, 517 502, Tirupati, India
2. Fuel Chemistry Division, Bhabha Atomic Research Centre, 400 085, Bombay, India
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| Abstract: | Isotopic exchange behaviour of bis(resacetophenone oxime) nickel(II) complex with nickel(II) in tri-n-butyl phosphate (TBP) and ethanol medium has been studied. The studies were carried out at different temperatures by varying the concentrations of both metal ion and the complex. Experimental observations showed that the complex is kinetically labile. Increase in temperature increases the isotopic exchange rate. Increase in concentration of either metal ion or complex results in significant increase of the reaction rate. |
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