Spin transition in a chainlike supramolecular iron(II) complex |
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| Authors: | Rajadurai Chandrasekar Schramm Frank Brink Susan Fuhr Olaf Ghafari Mohamed Kruk Robert Ruben Mario |
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| Institution: | Institute of Nanotechnology, Research Center Karlsruhe, D-76021 Karlsruhe, Germany. |
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| Abstract: | A one-dimensional supramolecular head-to-tail N+ -H...N-type hydrogen-bonded chain of the complex FeII(L)2H](ClO4)3.MeOH L = 4'-(4'-pyridyl)-1,2':6'1'-bis(pyrazolyl)pyridine] exhibits a reversible, thermally driven spin transition at 286 K with a hysteresis loop of ca. 2 K. |
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