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Crystallization Mechanism of 9,9-Diphenyl-dibenzosilole from Solids |
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| Authors: | Dr. Mingliang Li Dr. Xiaoge Wang Guozhi Wang Shizhao Ren Shuo Li Prof. Feng Wei Prof. Shouke Yan Prof. Xuefeng Guo Prof. Hailing Tu |
| Affiliation: | 1. GRIMAT Engineering Institute Co., Ltd, Beijing, 101407 P. R. China;2. Beijing National Laboratory for Molecular Sciences State Key Laboratory for Structural Chemistry of Unstable and Stable Species College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 P. R. China Department of Materials Science and Engineering College of Engineering, Peking University, Beijing, 100871 P. R. China;3. GRIMAT Engineering Institute Co., Ltd, Beijing, 101407 P. R. China State Key Laboratory of Advanced Materials for Smart Sensing, General Research Institute for Nonferrous Metals, Beijing, 100088 P. R. China;4. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, NO. 15, Beisanhuandong Road, Chaoyang District, Beijing, 100029 P. R. China.;5. Beijing National Laboratory for Molecular Sciences State Key Laboratory for Structural Chemistry of Unstable and Stable Species College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 P. R. China |
| Abstract: | Organic semiconductor (OSC) crystals have great potential to be applied in many fields, as they can be flexibly designed according to the demands and show an outstanding device performance. However, OSCs with the capacity of solid-state crystallization (SSC) are developing too slowly to meet demands in productions and applications, due to their difficulties in molecular design and synthesis, unclear mechanism and high dependence on experimental conditions. In this work, in order to solve the problems, we synthesized an organic semiconductor capable of SSC at room temperature by adjusting the relationship between conjugated groups and functional groups. The thermodynamic and kinetic properties have been studied to discover the model of film SSC. Moreover, it can be purposefully controlled to prepare the high-quality crystals, and their corresponding organic electronic devices were further fabricated and discussed. |
| Keywords: | crystallization mechanism field-effect transistors model organic semiconductors solid-state crystallization |