The kinetics and thermodynamics of surfactants in solvent sublation |
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| Authors: | Y-j Lu Yue-song Wang Y Xiong Xi-hai Zhu |
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| Institution: | (1) Chemistry and Biological Department, Normal School, Shengzhen University, Shengzhen 518060, P.R. China e-mail: yujuanlv@163.net, CN;(2) School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275, P.R. China, CN;(3) Institute of Chemical Metallurgy, Chinese Academy of Sciences, Beijing, 100080, CN |
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| Abstract: | Solvent sublation has been performed on very dilute solutions of one cationic surfactant, hexadecylpyridinium chloride (HPC), and one anionic surfactant, dodecylbenzenesulfonic acid (LBS). Some thermodynamic values were obtained, e.g. molecular areas, A0, which are 50.0 and 47.7 Å2/molecule, respectively, for HPC and LBS, and free adsorption energies, ΔG°ads, which are –33.17 and –43.58 kJ mol–1, respectively, for HPC and LBS. The kinetics were determined for a range of temperatures and gas flow-rates. Although the processes of solvent sublation of the two surfactants obey first-order kinetics, the respective adsorption mechanisms of HPC and LBS in the solvent sublation process were different. The pH and the presence of KCl and ethanol had no effect on the solvent sublation of LBS. The apparent active energy was calculated as 8.11 kJ mol–1. |
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