Cathode-catalyzed transesterification of alkylphosphonates |
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| Authors: | M E Niyazymbetov B Kostizella I Keitel K H Schwartz |
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| Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow;(2) Central Organic Chemistry Institute, Academy of Sciences of the German Democratic Republic, Berlin |
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| Abstract: | The cathodic electrolysis of aliphatic alcohols and alkylphosphonates in acetonitrile with 0.5 N Et4NClO4 as the base electrolyte leads to mono- and ditransesterified phosphonates. The yield and ratio of these products is a function of the nature of the starting reagents and amount of current passed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 200–204, January, 1991. |
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