Kinetic isotope effect during acid hydrogen exchange in σ-benzyl-π-cyclopentadienyliron dicarbonyl |
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Authors: | T. Yu. Orlova F. S. Yakushin V. N. Setkina |
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Affiliation: | (1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | ![]() Conclusions The kinetic isotope effect KD/KT was measured during acid hydrogen exchange in -C5H5-(CO)2Fe- -CH2C6H5. The obtained KD/KT value testifies in support of the generality of the mechanisms of hydrogen exchange in the benzene ring of this complex and in other derivatives of the benzene series.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 221–222, January, 1979. |
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