| 高分子-AlCuCl4膜及其气体透过行为探讨 |
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| 引用本文： | 施孝遹,潘光明,孙社营.高分子-AlCuCl4膜及其气体透过行为探讨[J].无机化学学报,1993,9(1):59-64. |
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| 作者姓名： | 施孝遹 潘光明 孙社营 |
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| 作者单位： | 中国科学院兰州化学物理研究所 兰州730000
(施孝遹，潘光明)，中国科学院兰州化学物理研究所 兰州730000(孙社营) |
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| 摘 要： | 把对一氧化碳具有选择吸附功能的液体吸附剂(AlCuCl_4-甲苯溶液和AlCuCl_4-Pst-甲苯溶液)引入到高分子(EC、Pst、ABS、CA)膜材料中,制成固体膜,考察了膜的气体透过性能,同时初步得出结果认为,膜中的AlCuCl_4以电荷转移配合物形式与高分子配位结合.
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| 关 键 词： | 膜 气体透过性能 高分子膜 AlCuCl4 |
| 收稿时间： | 1991/8/20 0:00:00 |
AN INVESTIGATION IN CHARACTERIZATION AND GAS PERMSELECTIVITIES OF POLYMER-AlCuCl4 MEMBRANE |
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| Shi Xiaoyu,Pan Guangming and Sun Sheying.AN INVESTIGATION IN CHARACTERIZATION AND GAS PERMSELECTIVITIES OF POLYMER-AlCuCl4 MEMBRANE[J].Chinese Journal of Inorganic Chemistry,1993,9(1):59-64. |
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| Authors: | Shi Xiaoyu Pan Guangming and Sun Sheying |
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| Institution: | Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou 730000,Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou 730000 and Lanzhou Institute of Chemical Physics, Academia Sinica, Lanzhou 730000 |
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| Abstract: | The liquid adsorbents possessing selective adsorbing function for carbon monoxide (AlCuCl4-tolueue solution and AlCuCl4-Pst-toluene solution) was incorporated into polymer membrane materials (EC, Pst, ABS, CA), then the gas separation membranes were made, and characterization their gas permselectivities were studied. The results showed that, the AlCuCl4 in membrane is linked with functional group of polymers as a charge-transfer complexes. |
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| Keywords: | membrane gas permeability charge-transfer complex coordination |
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