| 二碘化钐促进的二硫代氨基甲酸酯和硫代氨基甲酸酯的还原断裂反应 |
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| 引用本文： | 蒋华江,张永敏.二碘化钐促进的二硫代氨基甲酸酯和硫代氨基甲酸酯的还原断裂反应[J].有机化学,1995,15(5):481-486. |
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| 作者姓名： | 蒋华江 张永敏 |
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| 作者单位： | 杭州大学化学系 浙江(蒋华江)，杭州大学化学系 杭州(张永敏) |
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| 基金项目： | 国家自然科学基金，中国科学院上海有机化学研究所金属有机开放实验室基金 |
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| 摘 要： | 室温下SmI2-THF-HMPA-t-BuOH体系可顺利地将二硫代氨基甲酸酯还原断裂得到二硫醚和硫代甲酰胺; 同样条件下, 硫代氨基甲酸酯还原断裂得到二硫醚篅34The reductive cleavage of dithiocarbamic esters are promoted by the SmI2-HMPA-THF-t-BuOH System successfully to give disulfides and thiocarboxamides at room temperature in good yields; The reduction of thiocarbamic esters are also promoted by the same system to give disulfides and carboxamides.
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| 关 键 词： | 还原反应 二硫代氨基甲酸 P 甲酰胺 硫代甲酰胺 断裂反应 碘化钐 硫代氨基甲酸酯 二硫醚 |
Reductive cleavage of dithiocarbamic esters and thiocarbamic esters promoted by samarium(Ⅱ) diiodide |
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| JIANG Hua-Jiang,ZHANG Yong-Min.Reductive cleavage of dithiocarbamic esters and thiocarbamic esters promoted by samarium(Ⅱ) diiodide[J].Chinese Journal of Organic Chemistry,1995,15(5):481-486. |
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| Authors: | JIANG Hua-Jiang ZHANG Yong-Min |
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| Abstract: | The reductive cleavage of dithiocarbamic esters are promoted by the SmI2-HMPA -THF-t-BuOH System successfully to give disulfides and thiocarboxamides at room temperature in good yields; The reduction of thiocarbamic esters are also promoted by the same system to give disulfides and carboxamides. |
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| Keywords: | samarium diiodide thiocarbamic ester dithiocarbamic ester reductive cleavage disulfide thiocarboxamide carboxamide |
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