Halogenation of N-Substituted p-Quinonimines and p-Quinone Oxime Esters: II. Chlorination and Bromination of 4-Aroyl(arylsulfonyl)oxyimino-2-methyl-2,5-cyclohexadienones |
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Authors: | Avdeenko A. P. Glinyanaya N. M. Konovalova S. A. Goncharova S. A. |
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Affiliation: | (1) Donbass State Mechine-Building Academy, ul. Shkadinova 72, Kramatorsk, 84313, Ukraine |
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Abstract: | Halogenation of 4-aroyl(arylsulfonyl)oxyimino-2-methyl-2,5-cyclohexadienones yields Z,E-isomeric 4-aroyl(arylsulfonyl)oxyimino-5,6-dihalo-2-methyl-2-cyclohexenones and (E)-4-aroyl(arylsulfonyl)oxyimino-5,6-dihalo-6-methyl-2-cyclohexenones. Further chlorination leads to formation of (Z,E)-4-aroyl(arylsulfonyl)oxyimino-2,5,6-trichloro-6-methyl-2-cyclohexenones. |
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