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Joule-Thomson inversion curve prediction by using equation of state
摘    要:In this paper five equations of state are tested for checking their ability to predict the Joule-Thomson inversion curve.These five equations of state are:Mohsennia-Modarres-Mansoori(MMM),Ji-Lemp(JL),modified Soave-Redlich-Kwang(SRK)equation of state by Graboski(MSRK1),modified SRK equation of state by Peneloux and Rauzy(MSRK2),and modified Peng-Robinson (PR)equation of state by Rauzy(PRmr).The investigated equations of state give good prediction of the low-temperature branch of the inversion curve,except for MMM equation of state.The high-temperature branch and the peak of the inversion curve have been observed,in general,to be sensitive to the applied equation of state.The values of the maximum inversion temperature and maximum inversion pressure are calculated for each component used in this work.

收稿时间:14 March 2007

Joule-Thomson inversion curve prediction by using equation of state
Authors:Behzad Haghighi  Mohammad Reza Hussaindokht  Mohammad Reza Bozorgmehr  Naser Seyed Matin
Institution:1. Thermodynamic and Transport Properties Research Laboratory Department of Chemistry (T&TPRL), Birjand University, Birjand 97175-615, Iran;2. Department of Chemistry, Faculty of Sciences, Ferdowsi University, Mashad 91779-1436, Iran;3. Department of Chemistry, Faculty of Sciences, Islamic Azad University of Mashhad, Mashad, Iran;4. National Iranian Oil Company (NIOC), Research Institute of Petroleum Industry (RIPI), Tehran 18745-4391, Iran
Abstract:In this paper five equations of state are tested for checking their ability to predict the Joule-Thomson inversion curve.These five equations of state are:Mohsennia-Modarres-Mansoori(MMM),Ji-Lemp(JL),modified Soave-Redlich-Kwang(SRK)equation of state by Graboski(MSRK1),modified SRK equation of state by Peneloux and Rauzy(MSRK2),and modified Peng-Robinson (PR)equation of state by Rauzy(PRmr).The investigated equations of state give good prediction of the low-temperature branch of the inversion curve,except for MMM equation of state.The high-temperature branch and the peak of the inversion curve have been observed,in general,to be sensitive to the applied equation of state.The values of the maximum inversion temperature and maximum inversion pressure are calculated for each component used in this work.
Keywords:Equation of state  Joule-Thomson coefficient  Inversion curve
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