Rapid incorporation of radiobromine via the reaction of labeled sodium bromide with organoboranes |
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Authors: | G. W. Kabalka K. A. R. Sastry P. G. Pagni |
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Affiliation: | (1) Department of Chemistry, University of Tennessee, 37916 Knoxville, Tennessee, (USA) |
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Abstract: | Organoboranes react with82Br labeled sodium bromide in the presence of chloramine-T to yield the corresponding82Br labeled alkyl and aryl bromides. The reaction is rapid, proceeds under mild conditions, and tolerates a variety of functional groups. |
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