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| [Cu(TO)2(H2O)4](PA)2的合成和晶体结构 | |
| 引用本文： | 张建国,张同来,杨利,毛利秋,郁开北. [Cu(TO)2(H2O)4](PA)2的合成和晶体结构[J]. 无机化学学报, 2002, 18(3): 284-288 |
| 作者姓名： | 张建国 张同来 杨利 毛利秋 郁开北 |
| 作者单位： | 1. 北京理工大学机电工程学院,北京,100081 2. 中科院成都分院分析测试中心,成都,610041 |
| 摘 要： | [Cu(TO)2(H2O)4](PA)2 was prepared by mixing the aqueous solution of 1,2,4-triazol-5-one(TO) and Cu(PA)2. The molecular structure and crystal structure of the title complex was determined by X-ray single crystal diffraction method. The crystal is triclinic, space group with a=0.7321(1)nm,b=0.7474(2)nm,c=1.3649(3)nm;α=88.65(2)°,β=85.63(1)°,γ=63.35(1)°;V=0.6655(2)nm3,Z=1. The Cu2+ coordinated with two TO molecule through its 2-nitrogen atom and four water molecules and showed an octahedral configuration. |
| 关 键 词： | 制备 1 2 4-三唑-5-酮 铜配合物 晶体结构 |
| 修稿时间： | 2001-07-12 |
Preparation and Crystal Structure of [Cu(TO)2(H2O)4](PA)2 |
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| ZHANG Jian-Guo,ZHANG Tong-Lai,YANG Li,MAO Li-Qiu and YU Kai-Bei. Preparation and Crystal Structure of [Cu(TO)2(H2O)4](PA)2[J]. Chinese Journal of Inorganic Chemistry, 2002, 18(3): 284-288 | |
| Authors: | ZHANG Jian-Guo ZHANG Tong-Lai YANG Li MAO Li-Qiu YU Kai-Bei |
| Affiliation: | Department of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081,Department of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081,Department of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081,Department of Mechano-electric Engineering, Beijing Institute of Technology, Beijing 100081 and Analysis and Measurement Center, China Science Academy Chengdu Branch, Chengdu 610041 |
| Abstract: | |
| Keywords: | preparation 1 2 4-triazol-5-one(TO) copper complex crystal structure |
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