Crystal structure of a new mononuclear complex of Mn(II) with a bbbi ligand (bbbi = 1,4-bis(benzimidazol-1-yl)-2-butene) |
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| Authors: | G -H Cui T -F Liu C -H He and C -H Jiao |
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| Institution: | (1) College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, Henan, People’s Republic of China |
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| Abstract: | A new mononuclear complex Mn(bbbi)2(H2O)4(ClO4)2·(bbbi)2·(H2O)2 1 (bbbi = 1,4-bis(benzimidazol-1-yl)-2-butene) is synthesized under hydrothermal conditions and characterized by IR spectroscopy, elemental analysis, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, , a = 8.8478(7) ?, b = 15.0550(11) ?, c = 16.4310(12) ?, α = 108.657(7)°, β = 104.044(7)°, Γ = 99.317(7)°, V = 1942.2(3) ?3, Z = 1, final R = 0.0621. Each manganese atom is octahedrally coordinated by four aqua ligands and two nitrogen atoms of two distinct bbbi ligands. The molecule is stabilized by hydrogen bonding and π…π interactions. |
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