Synthesis ofN-substituted 2-(5,6,7,8-tetrafluoro-4-oxo-1,4-dihydroquinolin-3-yl)glyoxylic acids |
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Authors: | G A Obanin A S Fokin Ya V Burgart O V Ryzhkov Z E Skryabina V I Saloutin O N Chupakhin |
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Institution: | (1) Institute of Organic Synthesis, Ural Division of the Russian Academy of Sciences, 20 ul S. Kovalevskoy, 620219 Ekaterinburg, Russian Federation |
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Abstract: | Methods for the synthesis of the earlier unknownN-substituted 2-(5,6,7,8-tetrafluoro-4-oxo-1,4-dihydroquinolin-3-yl)glycoxylic acids their esters from copper chelate of ethyl
pentafluorobenzoylpyruvate were developed. The structure of intermediate ethyl 4-(R-amino)-2-oxo-3-pentafluorobenzoylbut-3-enoates
is discussed.
Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1234–1239, July, 2000. |
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Keywords: | ethyl pentafluorobenzoylpyruvate ethyl 4-(R-amino)-2-oxo-3-pentafluorobenzoylbut-3-enoates 3-ethoxalyl-5 6 7 8-tetrafluoroquinolin-4-ones N-substituted 2-(5 6 7 8-tetrafluoro-4-oxo-1 4-dihydroquinolin-3-yl)glyoxylic acids |
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