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Growth and spectroscopic characteristics of Nd-doped PbWO4 crystal
Authors:Wang Qing-Guo  Su Liang-Bi  Li Hong-Jun  Xiong Wei  Yuan Hui  Zheng Li-He  Xu Xiao-Dong  Wu Feng  Tang Hui-Li  Jiang Da-Peng  Xu Jun
Institution:1. Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China;2. Graduate University of the Chinese Academy of Sciences, Beijing 100039, China
Abstract:Nd-doped PbWO4 crystals are grown by using the modified Bridgman method. The spectroscopic properties of the crystals are investigated. The changes of the absorption band at 350 nm are discussed for samples annealed at 740℃ and 1040℃. The radiative lifetime of the 4F3/2 level is calculated by using the Judd--Ofelt theory according to the absorption spectrum of 0.5 at.% Nd-doped PbWO4 crystal. The spontaneous Raman scattering properties of the crystals are analysed.
Keywords:PbWO4  Bridgman method  Judd--Ofelt theory  Raman spectra
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