| 原位水热合成一个发光的烯烃铜(Ⅰ)配合物(英) |
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| 引用本文： | 杜楣,王锡森.原位水热合成一个发光的烯烃铜(Ⅰ)配合物(英)[J].无机化学学报,2005,21(6):941-944. |
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| 作者姓名： | 杜楣 王锡森 |
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| 作者单位： | 南京大学化学化工学院,南京,210093 |
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| 摘 要： | The solvothermal reaction of 1-(Benzyl diallylamine)-2-naphtholallyl ether and CuCI yields a unexpected copper(Ⅰ)-olefin complex, Cu6Cl6 (diallylamine) 1, which bears twelve-membered ring oligomeric structure and displays red fluorescent emission in the solid state at room temperature. CCDC: 272088.
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| 关 键 词： | 烯烃铜配合物 荧光特性 溶剂热 原位合成 |
| 收稿时间： | 2005/3/30 0:00:00 |
| 修稿时间： | 2005/5/10 0:00:00 |
A Luminescent Copper(Ⅰ)-Olefin Complex Obtained Through in situ Hydrothermal Ligand Synthesis |
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| DU Mei and WANG Xi-Sen.A Luminescent Copper(Ⅰ)-Olefin Complex Obtained Through in situ Hydrothermal Ligand Synthesis[J].Chinese Journal of Inorganic Chemistry,2005,21(6):941-944. |
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| Authors: | DU Mei and WANG Xi-Sen |
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| Institution: | School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 and School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 |
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| Abstract: | The solvothermal reaction of 1-(Benzyl diallylamine)-2-naphtholallyl ether and CuCl yields a unexpected copper(Ⅰ)-olefin complex, Cu6Cl6 (diallylamine) 1, which bears twelve-membered ring oligomeric structure and displays red fluorescent emission in the solid state at room temperature. CCDC: 272088. |
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| Keywords: | copper(Ⅰ)-olefin complex fluorescent solvothermal synthesis |
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