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Synthesis of ternary and quaternary CuInxGa1−xSe2 (0 ≤ x ≤ 1) semiconductor nanocrystals
Authors:Yu-Hsiang A. Wang   Changqing Pan   Ningzhong Bao  Arunava Gupta  
Affiliation:aDepartment of Chemistry and Center for Material for Information Technology, University of Alabama, 205 Bevill Building, Box 870209, Tuscaloosa, AL 35487, USA
Abstract:Semiconducting CuInxGa1−xSe2 nanocrystals (20–30 nm) have been synthesized over the whole composition range using a facile solution-based method. Depending on the synthesis conditions, the nanocrystals exhibit a cubic or spherical morphology with a narrow size distribution. The band gap increases with increasing Ga concentration and the values are close to those observed in the bulk.
Keywords:Chalcopyrite   Photovoltaic   Semiconductors   Nanocrystals
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