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Preparation of enantiopure inherently chiral calix[5]arenes
Institution:1. R&D Center for Pharmaceuticals, School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing 100081, PR China;2. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, PR China;1. Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, 1-14 Bunkyo, Nagasaki 852-8521, Japan;2. Department of Chemistry and Biological Science, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo, Sagamihara, Kanagawa 252-5258, Japan;1. Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey;2. Department of Chemistry, Hitit University, 19030 Corum, Turkey;1. Department of General and Physical Chemistry, University of Pécs, Ifjúság 6., H-7624 Pécs, Hungary;2. Department of Inorganic Chemistry and MTA-PTE Research Group for Selective Chemical Syntheses, University of Pécs, Ifjúság 6., H-7624 Pécs, Hungary;3. János Szentágothai Research Center, H-7624 Pécs, Ifjúság 20., Hungary;1. Department of Chemistry, Key Laboratory of Functional Inorganic Material Chemistry of Anhui Province, Anhui University, Hefei 230039, PR China;2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China
Abstract:Enantiopure inherently chiral calix5]arenes were successfully prepared by separation of their (R)-BINOL diastereomeric derivatives of the corresponding racemates by column chromatography instead of HPLC. A new type of inherently chiral calix5]arene was obtained.
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