Chiral ionic liquids,a renewal for the chemistry of chiral solvents? Design,synthesis and applications for chiral recognition and asymmetric synthesis |
| |
| Affiliation: | 1. UMR-CNRS 6507 Laboratoire de Chimie Moléculaire et Thioorganique, ENSICAEN, Université de Caen, 6 bd du Maréchal Juin, F-14050 Caen, France;2. UMR-CNRS 6014, Institut de Recherche en Chimie Organique Fine, Université de Rouen, rue Tesnière, F-76821 Mont Saint Aignan Cedex, France;1. Departamento de Química Analítica, Química Física e Ingeniería Química. Universidad de Alcalá, Ctra. Madrid-Barcelona Km. 33.600, 28871, Alcalá de Henares (Madrid), Spain;2. Instituto de Investigación Química Andrés M. del Río. Universidad de Alcalá, Ctra. Madrid-Barcelona Km. 33.600, 28871, Alcalá de Henares (Madrid), Spain;1. Department of Analytical Chemistry, China Pharmaceutical University, Nanjing 210009, China;2. Key Laboratory of Drug Quality Control and Pharmacovigilance (Ministry of Education), China Pharmaceutical University, Nanjing 210009, China;3. State Key Laboratory of Natural Medicines, China Pharmaceutical University, Nanjing 210009, China |
| |
| Abstract: | 
Chiral ionic solvents were almost unexplored before the last five years. This field which is of increasing importance could constitute a renewal for the chemistry of chiral solvents. So far reported examples are designed either from the chiral pool (aminoacids, hydroxyacids, amines, aminoalcohols, terpenes and alkaloids) or by asymmetric synthesis; they can bear central, axial or planar chirality. Modern applications in asymmetric synthesis, enzymatic chemistry, chiral chromatography and NMR are surveyed. Their use in the field of liquid crystals and for stereoselective polymerisation are also discussed. At the end of the article, a series of tables is compiled including all the CILs described to date and their physical properties. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
