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Investigation of electronic and optical properties in Al−Ga codoped ZnO thin films
Authors:Woojin LeeSungjin Shin  Dae-Ryong JungJongmin Kim  Changwoo NahmTaeho Moon  Byungwoo Park
Institution:a WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 151-744, Republic of Korea
b School of Electrical Engineering, Korea University, Seoul 136-713, Republic of Korea
Abstract:Electronic and optical properties of Al−Ga codoped ZnO thin films were investigated by post-annealing. The lowest resistivity of the Al-Ga codoped ZnO films was observed from the 450 °C-annealed sample. The Fermi-level shift of the Al−Ga codoped ZnO film was ∼0.6 eV from x-ray photoelectron spectroscopy, and the widening of optical-bandgap in the Al−Ga codoped ZnO film was ∼0.3 eV. The correlations of optical-bandgap with Fermi-level shift and conduction band filling were suggested by schematic band diagrams.
Keywords:Transparent conducting oxide  Al-Ga codoped ZnO  Fermi-level shift  Optical-bandgap
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