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Physicochemical and photocatalytic activities of self-assembling TiO2 nanoparticles on nanocarbons surface
Authors:Feng Wang  Kan Zhang
Institution:a Department of Applied Physics, Beijing Institute of Technology, Beijing 100081, China
b Key Laboratory of Cluster Science (Beijing Institute of Technology), Ministry of Education of China, Beijing 100081, China
c Department of Chemistry, Pohang University of Science and Technology, San 31, Hyojadong, Namgu, Pohang 790-784, Republic of Korea
d Department of Advanced Materials & Science Engineering, Hanseo University, Chungnam 356-706, Republic of Korea
Abstract:TiO2 nanoparticles were self-assembled on three different dimensional nanocarbon (SWCNT, C60 and graphene) surfaces by a uniform thermal reaction. The effective anchoring of TiO2 nanoparticles on the nanocarbon surfaces was characterized by FT-IR, XRD, XPS, TEM, Raman spectroscopy, PL and UV-Vis. By investigating the effect of different carbon nanostructures on TiO2 photocatalyst system, we found that the enhancing photocatalytic activities of nanocarbon/TiO2 (NT) nanocomposites have still related to great adsorbability and effective charge transfer by nanocarbon introduced, however, no more insights can be provided for peculiar properties on different nanostructures, although graphene by itself has an excellent structure and morphology.
Keywords:Nanocarbon  Photocatalytic activity  Thermal reaction  Charge transfer
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