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Synthesis of ( )-5α-Hydroxy-β-selinene and (-)-5β-Hydroxy-β-selinene

作者姓名：	Zhao Ming XIONG Gang ZHOU Yong Gang CHEN and Yu Lin LI

作者单位：	National Laboratory of Applied organic Chemistry and Institute of Organic Chemistry，Lanzhou University，Lanzhou 730000

摘要：	Eudesmanederivativeshavebeendrawingconsiderableattentionduetotheirwidespectrumofbiologicalproperties,particularlyantifeedant,cellgroWthinhibitoryandplantgroWthregulatingactivitiesl'2.Recently,twoepimericeudesmanederivatives( )-5a-hydroxy-6-selinene1and(-)-56-hydroxy-6-selinene2wereisolated3fromtheaerialpartsofCSubtraPicaFMell.,andtheirstructuresweredeterminedbyspectroscopicmethods.Herein,wereportafacilesynthesisofbothtwodiastereomers1and2from( )-dihydrocarvone3infivesteps,usingtheregioselect…
关键词：	Synthesis Sesquiterpenoid 5α-hydroxy-β-selinene 5β-hydroxy-β-selinene dihydrocarvone
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