Calculation of dipole moments in conjugated enamines by LCAO MO method |
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| Authors: | Ya F Freimanis I B Mazheika |
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| Institution: | (1) Institute of Organic Synthesis, AS LatvSSR, Riga |
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| Abstract: | Quantum-mechanical calculations were performed for a number of  -aminovinyl ketones, and their  -dipole moments were calculated. The results are compared with experimental values of 
exper
=exper- for 12 -aminovinyl ketones, and a linear correlation was obtained between the experimental and calculated values. On the basis of the results obtained, the conformation of the -electron system and the orientation of the substituents were determined. |
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