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神华煤直接液化残渣水蒸气和CO_2气化反应性研究
引用本文:楚希杰,李文,白宗庆,李保庆,陈皓侃.神华煤直接液化残渣水蒸气和CO_2气化反应性研究[J].燃料化学学报,2010,38(1).
作者姓名:楚希杰  李文  白宗庆  李保庆  陈皓侃
作者单位:1. 中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西,太原,030001;中国科学院研究生院,北京,100049
2. 中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西,太原,030001
基金项目:国家自然科学基金青年基金 
摘    要:分别对神华煤和神华煤直接液化残渣的水蒸气和CO2气化反应性进行了研究。结果表明,水蒸气气化反应中,煤半焦的反应性强于残渣半焦;CO2气化反应中,残渣半焦的反应性强于煤半焦。这主要是影响煤和残渣水蒸气和CO2气化反应性的关键因素不同。水蒸气气化反应受煤化程度的影响较大,而CO2气化反应受煤化程度的影响较小,受矿物质催化作用的影响大。

关 键 词:煤直接液化残渣  水蒸气气化  CO_2气化

Gasification reactivity of Shenhua direct liquefaction residue with steam and CO_2
CHU Xi-jie,LI Wen,BAI Zong-qing,LI Bao-qing,CHEN Hao-kan.Gasification reactivity of Shenhua direct liquefaction residue with steam and CO_2[J].Journal of Fuel Chemistry and Technology,2010,38(1).
Authors:CHU Xi-jie  LI Wen  BAI Zong-qing  LI Bao-qing  CHEN Hao-kan
Institution:CHU Xi-jie1,2,LI Wen1,BAI Zong-qing1,LI Bao-qing1,CHEN Hao-kan1 (1.State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyaun 030001,China,2.Graduate University of Chinese Academy of Sciences,Beijing 100049,China)
Abstract:The gasification reactivity of Shenhua coal char(CC) and Shenhua coal direct liquefaction residue char(RC) with CO2 and steam was studied using a fixed bed reactor.The results show that CC has a higher steam gasification activity than RC,while RC has a higher CO2 gasification activity than CC,which is due to different influencing factors for steam and CO2 gasification.For steam gasification the reactivity of char is mainly affected by coal rank,but for CO2 gasification the reactivity of char is mainly affec...
Keywords:liquefaction residue  steam gasification  CO_2 gasification
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