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| 水促进的三组分PBM反应合成三级胺 | |
| 引用本文： | 黄汉民. 水促进的三组分PBM反应合成三级胺[J]. 分子催化, 2014, 0(3): 197-203 |
| 作者姓名： | 黄汉民 |
| 作者单位： | 中科院兰州化学物理研究所 |
| 基金项目： | 国家自然科学基金项目（面上项目，重点项目，重大项目） |
| 摘 要： | 首次报道了甲醛衍生的胺缩醛和芳基硼酸在水的促进下,可以在没有催化剂的条件下高效的合成三级胺.在此基础上建立了一种利用多聚甲醛,二级胺和芳基或杂环硼酸合成三级胺的高效合成方法.此反应条件温和,操作简单,具有很好的底物适应性,目标产物的收率最高可达93%. |
| 关 键 词： | 芳基硼酸 胺缩醛 多聚甲醛 取代三级胺 PBM反应 |
| 收稿时间： | 2014-03-10 |
| 修稿时间： | 2014-03-26 |
A water promoted-PBM protocol for synthesize tertiary amines with arylboronic acids, paraformaldehyde and secondary amineswith arylboronic acids, paraformaldehyde and secondary amines |
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| HU Jian-hua;XIE Yin-jun;HUANG Han-min. A water promoted-PBM protocol for synthesize tertiary amines with arylboronic acids, paraformaldehyde and secondary amineswith arylboronic acids, paraformaldehyde and secondary amines[J]. Journal of Molecular Catalysis (China), 2014, 0(3): 197-203 | |
| Authors: | HU Jian-hua XIE Yin-jun HUANG Han-min |
| Affiliation: | Lanzhou Institute of Chemical Physics, CAS |
| Abstract: | A practical and efficient synthetic method for synthesis of benzylic tertiary amines by using arylboronic acids, paraformaldehyde and secondary amines was established in the absence of catalyst. This reaction is very simple and can be efficiently performed under mild conditions, which establishes a practical approach toward a wide range of benzylic tertiary amines. |
| Keywords: | Arylboronic acids aminals paraformaldehyde tertiary amines PBM reaction |
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