| 低聚醚磺酸锂／梳形聚醚复合物的单离子导电性 |
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| 引用本文： | 郑云贵,万国祥. 低聚醚磺酸锂／梳形聚醚复合物的单离子导电性[J]. 高分子学报, 1995, 0(3): 365-367 |
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| 作者姓名： | 郑云贵 万国祥 |
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| 作者单位： | 中国科学院成都有机化学研究所 610015 |
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| 摘 要： | ![]()
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| 关 键 词： | 聚醚 磺酸锂 单离子导体 梳形聚醚 |
| 收稿时间： | 1994-01-11 |
SINGLE-ION CONDUCTION OF LITHIUM OLIGOETHER SULFONATE/COMBLIKE POLYETHER COMPLEX |
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| ZHENG Yun-gui,WAN Guo-xiang. SINGLE-ION CONDUCTION OF LITHIUM OLIGOETHER SULFONATE/COMBLIKE POLYETHER COMPLEX[J]. Acta Polymerica Sinica, 1995, 0(3): 365-367 |
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| Authors: | ZHENG Yun-gui WAN Guo-xiang |
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| Affiliation: | Chengdu Institute of Organic Chemistry; Academia Sinica. Chengdu 610041 |
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| Abstract: | ![]()
A complex ionic conductor was prepared by solution complexation of lithium methoxy oligo (oxyethylene) sulfonate (SOL8, where & is the repeating unit of oxyethylene) with comblike copolyether poly [methoxy oligo (oxyethylene)methacrylate-co-acrylamide] [P(MEO16-AM)]. The composition dependences of glass transition temperature,crystallinity as well as conducti-vity of the complex were investigated. DC polarization showed that the complex shows a stable polarization characteristic. Polarization reversing method confirmed that the complex has a cati-onic transference number of 0.99. |
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