| [Cu(PTA)(Phen)2](p-MBA)(H6O)配合物的合成、晶体结构及电化学分析 |
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| 引用本文： | 杨颖群,李昶红,陈志敏,邝代治,李薇,陈满生.[Cu(PTA)(Phen)2](p-MBA)(H6O)配合物的合成、晶体结构及电化学分析[J].无机化学学报,2006,22(6):1103-1107. |
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| 作者姓名： | 杨颖群 李昶红 陈志敏 邝代治 李薇 陈满生 |
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| 作者单位： | 1. 衡阳师范学院化学与材料科学系,衡阳,421008
2. 湖南工学院化学化工系,衡阳,421008 |
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| 基金项目： | 湖南省基础性研究项目;衡阳师范学院校科研和教改项目 |
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| 摘 要： | The crystal structure of the title complex with the stoichiometric formula Cu(PTA)(Phen)2](p-MBA)(H6O) (Phen=1,10-phenanthroline, PTA=terephthalic acid, p-MBA=p-toluic acid) has been determined by single-crystal X-ray diffraction. The crystal (C48H40CuN4O10, Mr=896.38) belongs to the monoclinic space group C2/c, with the following crystallographic parameters: a=1.778 6(3) nm, b=1.912 5(3) nm, c=1.389 9(2) nm, β=114.686(2)°, V=4.295 7(12) nm3, Dc=1.386 g·cm-3, Z=4, μ(Mo Kα)=0.574 mm-1, F(000)=1 860, final GooF=1.019, R=0.054 0, wR=0.148 3 for 2 644 observed reflections (I>2σ(I)). The crystal structure shows that the copper(Ⅱ) ion is coordinated with two oxygen atoms from one terephthalic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 298809.
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| 关 键 词： | 铜(Ⅱ)配合物 晶体结构 电化学性质 |
| 文章编号： | 1001-4861(2006)06-1103-05 |
| 收稿时间： | 2005-12-05 |
| 修稿时间： | 2006-04-03 |
Synthesis, Crystal Structure and Electrochemical Properties of Copper(Ⅱ) Complex [Cu(PTA)(Phen)2](p-MBA)(H2O) |
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| YANG Ying-Qun,LI Chang-Hong,CHEN Zhi-Min,KUANG Dai-Zhi,LI Wei and CHEN Man-Sheng.Synthesis, Crystal Structure and Electrochemical Properties of Copper(Ⅱ) Complex [Cu(PTA)(Phen)2](p-MBA)(H2O)[J].Chinese Journal of Inorganic Chemistry,2006,22(6):1103-1107. |
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| Authors: | YANG Ying-Qun LI Chang-Hong CHEN Zhi-Min KUANG Dai-Zhi LI Wei and CHEN Man-Sheng |
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| Institution: | Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008 and Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang, Hunan 421008 |
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| Abstract: | The crystal structure of the title complex with the stoichiometric formula Cu(PTA)(Phen)2](p-MBA)(H2O) (Phen=1,10-phenanthroline, PTA=terephthalic acid, p-MBA=p-toluic acid) has been determined by single-crystal X-ray diffraction. The crystal (C48H40CuN4O10, Mr=896.38) belongs to the monoclinic space group C2/c, with the following crystallographic parameters: a=1.778 6(3) nm, b=1.912 5(3) nm, c=1.389 9(2) nm,3=114.686(2)°, V=0.148 3 for 2 644 observed reflections (I＞2σ(l)). The crystal structure shows that the copper(Ⅱ) ion is coordinated with two oxygen atoms from one terephthalic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 298809. |
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| Keywords: | crystal structure electrochemical property |
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