Nucleophilic aromatic substitution using Et3SiH/cat. t-Bu-P4 as a system for nucleophile activation |
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| Authors: | Ueno Masahiro Yonemoto Misato Hashimoto Masahiro Wheatley Andrew E H Naka Hiroshi Kondo Yoshinori |
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| Affiliation: | Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki Aza Aoba 6-3, Sendai, 980-8578, Japan. |
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| Abstract: | ![]()
A novel type of deprotonative arylation of nucleophiles was conducted using Et(3)SiH/cat. t-Bu-P4 and the powerful S(N)Ar reactions of aryl fluorides were accomplished using alcohols and malonates as nucleophiles. |
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