Unprecedented binding and activation of CS2 in a dinuclear copper(I) complex |
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| Authors: | Haack Peter Limberg Christian Tietz Thomas Metzinger Ramona |
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| Affiliation: | Humboldt-Universit?t zu Berlin, Institut für Chemie, Brook-Taylor-Str. 2, 12489 Berlin, Germany. |
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| Abstract: | The first structural characterisation of a copper-carbondisulfide complex revealed a hitherto unknown binding mode for CS(2): it interacts with two metal centres (Cu(I)) simultaneously via both C=S π bonds. DFT calculations showed that complex formation occurs mainly due to a donation of electron density from the copper centres into the C=S π* orbitals. |
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