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Equilibrium theory for the hard-core systems
Authors:Shigeru Shinomoto
Affiliation:(1) Department of Physics, Faculty of Science, Tohoku University, 980 Sendai, Japan
Abstract:
It is found that the density expansion in the argument of the exponential function gives a fine convergence on the equation of state of the hard-sphere system. The pair distribution function and the equation of state is constructed by an intuitive kinetic theoretical method. The equation of state of the hard-core system with attractive potential is constructed semiempirically with the aid of this simple analytical result, and Kamerling-Onnes' constant of the critical point is obtained analytically.
Keywords:Equation of state  pair distribution function  cluster expansion  kinetic theory  hard-sphere system  critical point
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