Addition of mercaptans to acetylenic γ-hydroxy ketones |
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| Authors: | A. S. Medvedeva L. P. Safronova M. G. Voronkov |
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| Affiliation: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions Both the nucleophilic and the free radical addition of n-butyl mercaptan to acetylenic -hydroxy ketones (1,1-disubstituted derivatives of 2-pentyn-1-ol-4-one) lead to the formation of the corresponding 1,1-disubstituted derivatives of 2-butylthio-2-penten-1-ol-4-one in 41–65% yield.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1669–1670, July, 1973. |
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