|
|||||
|
|
Relative raman line intensities for H2 and for D2. Correction factors for molecular non-rigidity |
|
| Authors: | Lap M Cheung David M Bishop |
| Institution: | Department of Chemistry, University of Ottawa, Ottawa, Canada K1N 9B4 Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA |
| Abstract: | Ab initio calculations are presented for H2 and D2 relative Raman intensities originating from common rotational levels for both vibrational-rotational and pure rotational transitions. Factors f(J) required to correct measured intensities for molecular non-rigidity (e.g. in temperature measurements) are tabulated. The calculations are compared with literature perturbation-theory equations (significant differences at large J in vibration-rotation) and with experiment. |
| Keywords: | Present address: Chemical Engineering Division Argonne National Laboratory Argonne Illinois 60439 USA |
| 本文献已被 ScienceDirect 等数据库收录！ | |