The first structurally characterized N-heterocyclic carbene complex with a ligand derived from pyrimidine |
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| Authors: | Björn Hildebrandt |
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| Institution: | Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, 40225 Düsseldorf, Germany |
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| Abstract: | Oxidative addition of N-alkyl-2-halopyrimidinium cations to Pd(PPh3)4] gives straightforward access to the cationic complexes (PPh3)2(NHC)PdX]BF4 (3a,b) with pyrimidine-derived NHC-ligands. The new complexes were fully characterized including X-ray crystallography. |
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| Keywords: | NHC Palladium Pyrimidine |
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