Alkynyl derivatives of gold complexes containing C6H3-5-Me-2-EPh2 (E = P, As) ligands |
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Authors: | Suresh K Bhargava Kunihiko Kitadai Steven H Privér Jörg Wagler |
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Institution: | a School of Applied Sciences (Applied Chemistry), RMIT University, GPO Box 2476V, Melbourne, Victoria 3001, Australia b Department of Chemistry, Toho University, Chiba, Japan c Institut für Anorganische Chemie, Technische Universität Bergakademie, Freiberg D-09596, Germany |
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Abstract: | Au2Cl2{μ-2,2′-Ph2As(5,5′-Me2C6H3C6H3)AsPh2}] reacts with phenylacetylene or ethynylferrocene to give the corresponding digold(I) bis(alkynyl) derivatives Au2(CCR)2{μ-2,2′-Ph2As(5,5′-Me2C6H3C6H3)AsPh2}] R = Ph (4), Fc (5)]. In contrast, products resulting from the reaction with 1,3- or 1,4-diethynylbenzene (deb) depend markedly on the dichlorodigold(I) complex to ligand ratio. When an excess of alkyne is used, the expected bis(alkynyl) complexes Au2X2{μ-2,2′-Ph2As(5,5′-Me2C6H3C6H3)AsPh2}] X = 1,3-deb (6), 1,4-deb (7)] are obtained, but when using a 1:1 molar ratio poorly soluble, presumably polymeric, species are formed. Attempts to prepare a digold(II) bis(alkynyl) derivative by treatment of Au2Cl2(μ-C6H3-5-Me-2-PPh2)2] with ethynylferrocene in the presence of NaOMe gives a mixture of species, the recrystallization of which yielded a crystal of {2-(FcCC)-4-MeC6H3PPh2}Au(CCFc)] (1). The reaction of Au2Cl2(μ-C6H3-5-Me-2-AsPh2)2] with phenylacetylene, 1,3- or 1,4-deb gives a mixture of unidentified products. |
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Keywords: | Gold alkynyl compound Arsenic ligand Mö ssbauer spectroscopy |
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