Investigation of silyl-substituted alkylthioacetates by IR and UV spectroscopy,1H and29Si NMR,and mass spectrometry |
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| Authors: | M G Voronkov S V Basenko R G Mirskov É I Brodskaya D D Toryashinova V A Pestunovich M F Larin V Yu Vitkovskii |
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| Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions The IR, UV, NMR, and mass spectra of silyl-substituted alkylthioacetates have been investigated. Intramolecular coordination of the carbonyl group with the silicon atom has been shown to exist in molecules of trifluoroaeetylthiomethylsilane in the condensed state and in a polar solvent (acetonitrile).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2224–2228, October, 1985. |
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