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Synthesis and structure of 16 pi octaalkyltetraphenylporphyrins |
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| Authors: | Yamamoto Yohsuke Yamamoto Akihiro Furuta Shin-ya Horie Masanori Kodama Megumi Sato Wataru Akiba Kin-ya Tsuzuki Seiji Uchimaru Tadafumi Hashizume Daisuke Iwasaki Fujiko |
| Institution: | Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan. yyama@sci.hiroshima-u.ac.jp |
| Abstract: | The oxidized octaethyltetraphenylporphyrin (1, OETPP) and the corresponding newly prepared octaisobutyltetraphenylporphyrin (3, OisoBuTPP) could be isolated from the reaction of OETPPLi2 (or OisoBuTPPLi2) with SOCl2. The X-ray analysis and the characteristic UV-vis spectra of 1 and 3 revealed that these are the first examples of 16 pi nonaromatic porphyrins. |
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