A mild,simple and efficient method for selectiveα-monobromination of 1,3-diketones and β-ketoesters using pyridinium bromochromate |
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作者姓名: | Yaghoub Sarrafi Marzieh Sadatshahabi Kamal Alimohammadi |
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作者单位: | Department of Chemistry, Mazandaran University, Babolsar, Iran |
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基金项目: | support from the Research Council of Mazandaran University |
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摘 要: | Pyridinium bromochromate has been found to be a highly efficient and selective reagent for theα-monobromination of 1,3-diketones andβ-keto-esters in the absence of base,Lewis acid,or other catalyst.The products were formed in high to excellent yields under mild reaction conditions and in short reaction times.
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关 键 词: | α-Monobromination β-Ketoesters |
收稿时间: | 2008-09-17 |
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