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Origin and meaning of the Fermi contact interaction
Authors:Werner Kutzelnigg
Institution:(1) Lehstuhl für Theoretische Chemie, Ruhr-Universität Bochum, D-4630 Bochum, Germany
Abstract:The Fermi-contact interaction (FCI) can easily be derived from 1st order perturbation theory applied to the non-relativistic wave equation for a spin-(1/2) particle of Lévy-Leblond, with the nuclear spin described by the field of an ldquoexternalrdquo magnetic dipole, and it results from the fact that the ldquoturn-over-rulerdquo for the operator 
$$\vec \sigma \vec p$$
is only valid if the derivatives implicit in 
$$\vec p$$
are taken ldquoin the distribution senserdquo. If one avoids to apply the turn-over-rule, the FCI is obtained without the need to introduce a ldquodelta-functionrdquo. It is also shown that the formulation of a magnetic point dipole as the limit of an extended nucleus directly leads to the FCI. Traditional methods of the derivation of the FCI are analyzed in the light of this new interpretation. It is then explained why the perturbation expansions in powers of the magnetic moment of the nucleus necessarily diverges, but that the expression for the 1st order energy on which the concept of the FCI is based, can nevertheless be justified by means of the Hellmann-Feynman theorem with a correction term if singular wave functions are involved. Finally some comments on a theory beyond first order are made.Dedicated to Professor J. Koutecký on the occasion of his 65th birthday
Keywords:Fermi contact interaction    vy-Leblond equation  Hyperfine interaction  Hellmann-Feynman theorem  Perturbation theory
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