Two orthopalladated chromophores

The title compounds, {5‐(di­methyl­amino)‐2‐N‐(4‐methoxy­phenyl)­imino­methyl]­phenyl}N‐(4‐methoxy­phenyl)‐4‐nitro­salicyl­aldiminato]­palladium(II), Pd(C₁₄H₁₁N₂O₄)(C₁₆H₁₇N₂O)], (I), and 4‐(diethyl­amino)‐N‐(4‐methoxy­phenyl)­sali­cyl­aldiminato]{2‐N‐(4‐methoxy­phenyl)­imino­methyl]‐5‐nitrophenyl}palladium(II) di­chloro­methane hemisolvate, Pd(C₁₄H₁₁N₂O₃)(C₁₈H₂₁N₂O₂)]·0.5CH₂Cl₂, (II), both contain push–pull chromophores coordinated to Pd in a square‐planar arrangement. In both compounds, the five‐membered orthopalladated ring is essentially planar, while the coordinated six‐membered ring is not. Deviations from a coplanar arrangement of the phenyl­ene rings of the coordinated Schiff bases are observed in both (I) and (II) as a result of intramolecular steric interactions.