| 1,10-邻菲咯啉取代苷脲及其一维Ag(Ⅰ)配位聚合物的合成及晶体结构 |
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| 引用本文： | 陈明华,张云黔,薛赛凤,陶 朱,祝黔江.1,10-邻菲咯啉取代苷脲及其一维Ag(Ⅰ)配位聚合物的合成及晶体结构[J].无机化学学报,2010,26(7):1264-1268. |
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| 作者姓名： | 陈明华 张云黔 薛赛凤 陶 朱 祝黔江 |
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| 作者单位： | 1. 贵州省大环化学及超分子化学重点实验室,贵州大学,贵阳,550025;兴义师范学院化学生物系,兴义,562400
2. 贵州省大环化学及超分子化学重点实验室,贵州大学,贵阳,550025 |
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| 基金项目： | 国家自然科学基金资助项目 |
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| 摘 要： | 合成了1,10-邻菲咯啉取代苷脲(L),并用L与硝酸银反应得到一维配位聚合物AgLNO3]n,利用X-射线衍射方法测定了它们的晶体结构。L:单斜晶系,空间群P21/c,a=1.8545nm,b=1.2504nm,c=1.2818nm,β=108.476°,V=2.8192nm3,Z=7,F(000)=1176,finalGOF=1.093,R1=0.060,wR2=0.1654,。AgLNO3]n:正交晶系,空间群Pca21,a=1.55149nm,b=1.04907nm,c=1.15892nm,V=1.8863nm3,Z=4,F(000)=1024,finalGOF=1.038,R1=0.042,wR2=0.110。晶体结构表明配体L与Ag髣形成了一维配位聚合物AgLNO3]n。
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| 关 键 词： | 1，10-邻菲咯啉取代苷脲 Ag(Ⅰ)配合物 晶体结构 一维配位聚合物 |
Synthesis and Crystal Structure of 1,10-Phenanthroline Substituted Glycoluril and Its 1D Complex Polymer with Silver(I) Ion |
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| CHEN Ming-Hu,ZHANG Yun-Qian,XUE Sai-Feng,TAO Zhu and ZHU Qian-Jiang.Synthesis and Crystal Structure of 1,10-Phenanthroline Substituted Glycoluril and Its 1D Complex Polymer with Silver(I) Ion[J].Chinese Journal of Inorganic Chemistry,2010,26(7):1264-1268. |
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| Authors: | CHEN Ming-Hu ZHANG Yun-Qian XUE Sai-Feng TAO Zhu and ZHU Qian-Jiang |
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| Institution: | Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025; Department of Chemistry and Biological, Xingyi Normal College, Xingyi, Guizhou 562400,Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025,Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025,Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025 and Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025 |
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