| 乙酐的醇解反应和集团结构适应性 |
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| 引用本文： | 金松寿,胡科诚,顾沁. 乙酐的醇解反应和集团结构适应性[J]. 浙江大学学报(理学版), 1988, 15(1): 69-73 |
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| 作者姓名： | 金松寿 胡科诚 顾沁 |
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| 摘 要： | 本文用集团结构适应性原理研究乙酐在CH_3OH、C_2H_5OH和n-C_3H_7OH等14种醇中的醇解反应机理,并对乙酐的醇解反应与醇的分子结构之间的关系进行了探讨.ROH的自身缔合作用不利于乙酐的醇解反应.
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| 关 键 词： | 溶剂效应 动力学 乙肝醇解反应 |
Alcoholysis of Acetyl Anhydride and the Adaptabilitv of Group Structure |
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| Jin Songshou Hu Kecheng Gu Qin. Alcoholysis of Acetyl Anhydride and the Adaptabilitv of Group Structure[J]. Journal of Zhejiang University(Sciences Edition), 1988, 15(1): 69-73 |
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| Authors: | Jin Songshou Hu Kecheng Gu Qin |
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| Affiliation: | Jin Songshou Hu Kecheng Gu Qin |
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| Abstract: | The reaction mechanism of alcoholysis of acetyl anhydride in 14 ROH has been investigated with the help of adaptabitity theory of group structure. The relationship between the structure of ROH and the specific reaction rate is correlated and discussed. It is found that the strong interaction between alcohol molecules, will depress the reaction rate. |
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| Keywords: | solvent effect kinetics alcoholysis of acetyl anhydride |
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