Syntheses and Crystal Structures of two Ring—like {Mo18}Cluster Compounds |
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引用本文: | 詹晓平,杨文斌,吴鼎铭,吴传德,余雅琴,张全争,卢灿忠.Syntheses and Crystal Structures of two Ring—like {Mo18}Cluster Compounds[J].结构化学,2003,22(1):70-76. |
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作者姓名: | 詹晓平 杨文斌 吴鼎铭 吴传德 余雅琴 张全争 卢灿忠 |
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作者单位: | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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基金项目: | the National Natural Science Foundation of China (20073048),NSF of Fujian province (2002F015) and the Chinese Academy of Sciences |
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摘 要: | 1INTRODUCTIONThepolyoxomolybdateshavebeenwidelyresearchedinmanyfieldssuchascatalysis,biology,medicineandmaterialsciencebecauseoftheirrichphysicalandchemicalproperties1].Thoughmanypolyoxomolybdateshavebeenreported2],furtherresearchisstillnecessaryforthestudyof搑eduction-oxidation-reconstitution?self-assemblyprocesses3,4].Polyoxomolybdatesarenormallybuiltupundersuitableconditionsbyafewbuildingblockssuchas{Mo2},{Mo8}and{Mo9}inself-assemblyway5,6].The{Mo18}clustershaveseveralstructuralty…
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关 键 词: | 钼配合物 合成 晶体结构 C8H103O102Na2S2Mo18 |
Syntheses and Crystal Structures of two Ring-like {Mo18} Cluster Compounds |
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Abstract: | Sodium molybdate was reduced to produce ring-like compounds in the presence of carboxylic acids. Compound 1: Na8(H2O)28(H3O)+{Na(DMSO)2MoVI10MoV8O52(OH)4(CH3C- OO)2]}11H2O (C8H103O102Na9S2Mo18, Mr = 3829.85), where the {Mo18} ring is built up by two acetic acids connecting two {Mo9} building blocks and the 1-D chain of 1 is formed through the coordinated sodium cations. Crystal data: triclinic, space group P, a = 11.3228(2), b = 15.4170(2), c = 16.7209(3) ? a = 113.006(1), b = 108.455(1), g = 92.430(1), V = 2501.98(7) 3, Z = 1, Dc = 2.542 g/cm3, F(000) = 1854, (MoKa) = 2.381 mm-1, T = 293(2) K, final R = 0.0532 and wR = 0.1203 for 7291 observed reflections with I > 2(I) from 8775 independent reflections. Compound 2: Na8(H2O)22(H3O)+{Na(DMSO)2MoVI10MoV8O52(OH)4(C2H5COO)2]}10H2O (C10H93O94Na9- S2Mo18, Mr = 3715.79). Crystal data: monoclinic, space group C2/m, a = 18.044(1), b = 25.944(2), c = 10.4087(6) ? b = 106.613(2), V = 4669.3(5) 3, Z = 2, Dc = 2.643 g/cm3, F(000) = 3584, (MoKa) = 2.542 mm-1, T = 293(2) K, final R = 0.0536 and wR = 0.1621 for 4617 observed reflections with I > 2(I) from 5398 independent reflections. Similar to 1, the {Mo18} ring is built up by two {Mo9} building blocks that are connected up by two propanoic acids and these {Mo18} rings are further linked into a two-dimensional layer through the coordinated sodium cations. |
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Keywords: | polyoxomolybdate cluster ring-like compound self-assembly |
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