Some aspects of solution chemistry in liquid mixtures of inorganic salts with water |
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| Affiliation: | 1. Ural Federal University (named after the First President of Russia B.N.Yeltsin), ul. Mira 19, Yekaterinburg, 620002, Russia;2. Ural Institute of State Fire Service of EMERCOM of Russia, Yekaterinburg, ul. Mira 22, 620062, Russia;3. Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, ul. S.Kovalevskoy 18, Yekaterinburg, 620041, Russia;4. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620990, Russia;1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, PR China;2. Department of Chemical and Petroleum Engineering, University of Wyoming, Laramie, WY 82071, USA;3. School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA;4. Nanjing AIREP Environmental Protection Technology Co., Ltd, Nanjing, Jiangsu 210091, PR China;1. Ioffe Institute, Polytekhnicheskaya 26, 194021, St.-Petersburg, Russia;2. Peter the Great St. Petersburg Polytechnic University, Polytekhnicheskaya 29, 195251, St.-Petersburg, Russia;3. Institute of Physics, Wrocław University of Technology, W. Wyspiańskiego 27, 50-370 Wrocław, Poland;1. Department of Chemistry and Polymer Science, Stellenbosch University, Private Bag X1, Matieland, 7602, South Africa;2. Chemistry Department, Katholieke Universiteit Leuven, Celestijnenlaan 200F, B-3001, Heverlee, Belgium |
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| Abstract: | Experimental and theoretical investigations of some thermodynamic, transport and structural properties of very concentrated aqueous electrolyte solutions are reviewed. Attention is focussed on the range of concentrations between anhydrous molten salts and the hydrate melts. In this region, the hydration shells of the ions are incomplete, and ion-ion, ion-water, and water-water interactions must be considered. Extensions of the Debye-Huckel theory are not valid in this region, and models based on anhydrous molten salts may be useful. |
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