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Role of imino group in photochemical reactions of Fischer carbene complexes
Authors:Pedro J. Campos
Affiliation:Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, Unidad Asociada al C.S.I.C.; Madre de Dios, 51, E-26006 Logroño, Spain
Abstract:The photochemical cycloaddition of Fischer iminecarbene complexes bearing two kinds of substituent, imine and alkoxy or amino, has been explored with alkenes and alkynes. It was found that annulated product without CO insertion is formed.
Keywords:Fischer iminecarbene   Photochemistry   Alkene   Alkyne
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