Transition metal σ-complexes in organic synthesis. 4. Cross coupling of allyl esters and allyl aryl sulfones with organotitanium compounds in the presence of palladium complexes |
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| Authors: | A. N. Kasatkin A. N. Kulak G. A. Tolstikov S. I. Lomakina |
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| Affiliation: | (1) Institute of Chemistry, Bashkir Scientific Center, Ural Branch, Academy of Sciences of the USSR, Ufa |
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| Abstract: | ![]()
Conclusions The reactions of organotitanium compounds PhTi(OPr-i)3 and MeTi(OPr-i)3 with allyl acetates, allyl phenyl ethers, allyl aryl sulfones, and allylic tosylates and mesylates are catalyzed by Pd complexes and lead to the formation of cross-coupling products.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2159–2166, September, 1988. |
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