Structural and conformational studies on citreoviridinol and isocitreoviridinol: syntheses of some 2,6-dioxabicyclo[3.2.1]octanes期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Structural and conformational studies on citreoviridinol and isocitreoviridinol: syntheses of some 2,6-dioxabicyclo[3.2.1]octanes

Authors:	Shigeru Nishiyama Yoshikazu Shizuri Daizo Imai Shosuke Yamamura Yukimasa Terada Masatake Niwa Kazuaki Kawai Hideyuki Furukawa

Affiliation:	Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi, Yokohama, Japan;Faculty of Pharmacy, Meijo University, Tempaku-ku, Nagoya, Japan

Abstract:	Isocitreoviridinol has been newly isolated from the mycelium of $Penicillium citreo-viride$ B. (IFO 6050) together with citreoviridinol, and their stereostructures have also been elucidated by means of chemical method: the 2,6-dioxabicyclo[3.2.1]octanes have been made, one of which is regarded as a promising synthetic intermediate of citreoviridinol. In addition, isocitreoviridinol diacetate has been derived from citreoviridin in 3 steps.

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