Ring-forming reaction via regioselective intramolecular insertion by (phenylthio) carbene into α c-h bond of alkoxides |
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| Authors: | Toshiro Harada Eiji Akiba Kohji Tsujimoto Akira Oku |
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| Institution: | Department of Chemistry, Kyoto Institute of Technology Matsugasaki, Sakyo-ku, Kyoto 606, Japan |
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| Abstract: | ω-(Phenylthio)-ω-chloroalkyl acetates were allowed to react with MeLi (3.2 equiv) to give 2-(phenylthio) cycloalkanols which were produced by the regioselective intramolecular insertion by (phenylthio) carbenes. |
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