Evidence for single electron transfer in metal-halogen exchange. The reaction of organolithium compounds with alkyl halides. |
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| Authors: | EC Ashby Tung N Pham Bongjin Park |
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| Institution: | School of Chemistry, Georgia Institute of Technology Atlanta, GA 30332 U.S.A. |
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| Abstract: | The reaction of -BuLi with cyclizable 1° and 2° alkyl halide radical probes at low temperature produced stab]e cyclized and uncyclized organolithium products as well as cyclized hydrocarbons which clearly indicate the presence of radical intermediates during the course of these reactions. |
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