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Regioselective openings of 2,3-epoxy acids with organocuprates |
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| Authors: | J.Michael Chong K.Barry Sharpless |
| Affiliation: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts U.S.A. |
| Abstract: | Lithium organocuprates react with 3-alkyl-2,3-epoxy acids (glycidic acids) to afford the products of ring-opening in good yield. The regiochemistry of ring-opening is dependent on the stereochemistry of the epoxy acid. |
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