Electronic structure and physical properties of ScN in pressure: density-functional theory calculations |
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Authors: | Guan Peng-Fei Wang Chong-Yu and Yu Tao |
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Institution: | Central Iron and Steel Research Institute, Beijing 100081, China; China Centre of Advanced Science and Technology (World
Laboratory), Beijing 100190, China; Department of Physics, Tsinghua University, Beijing
100084, China |
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Abstract: | Local density functional is investigated by using the full-potential
linearized augmented plane wave (FP-LAPW) method for ScN in the
hexagonal structure and the rocksalt structure and for hexagonal
structures linking a layered hexagonal phase with wurtzite structure
along a homogeneous strain transition path. It is found that the
wurtzite ScN is unstable and the layered hexagonal phase, labelled as
$h_{\rm o}$, in which atoms are approximately fivefold coordinated,
is metastable, and the rocksalt ScN is stable. The electronic
structure, the physical properties of the intermediate structures
and the energy band structure along the transition are presented. It
is found that the band gaps change from 4.0 to 1.0\,eV continuously
when $c/a$ value varies from 1.68 to 1.26. It is noticeable that the
study of ScN provides an opportunity to apply this kind of material
(in wurtzite$h$]-derived phase). |
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Keywords: | full-potential linearized
augmented plane wave (FLAPW) band gap phase transition |
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